Styrene → 1,1-Diphenylethylene

HRID 68104Notes

Reaction equation

HRID 68104 reaction equation
C=Cc1ccccc1.O=S(=O)(Oc1ccccc1)C(F)(F)F>CC(C)(C)P1CN(c2ccc(C(F)(F)F)cc2)CP(C(C)(C)C)CN(c2ccc(C(F)(F)F)cc2)C1.CCN(CC)CC.CN(C)C=O.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>C=C(c1ccccc1)c1ccccc1.COc1cc(OC)cc(OC)c1.C(=C\c1ccccc1)/c1ccccc1

Participants

9

Reactant 2

HCID 7501StyreneHCID 548641Phenyl Trifluoromethanesulfonate

Product 3

HCID 107401,1-DiphenylethyleneHCID 693011,3,5-TrimethoxybenzeneHCID 638088trans-Stilbene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 1778483303,7-Di-tert-butyl-1,5-bis(4-(trifluoromethyl)phenyl)-1,5,3,7-diazadiphosphocaneCatalystHCID 6228DimethylformamideSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-eecb993fad7f42d3809d0c093298a57d
Source dataset
Styrene Mizoroki-Heck

Reaction notes

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