Styrene → 1,1-Diphenylethylene

HRID 68110Notes

Reaction equation

HRID 68110 reaction equation
C=Cc1ccccc1.O=S(=O)(Oc1ccccc1)C(F)(F)F>Cc1cc(C)c(-n2cc[n+](-c3c(C)cc(C)cc3C)c2)c(C)c1.[Cl-].CC(C)(C)[O-].[K+].CCN(CC)CC.CN(C)C=O.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>C=C(c1ccccc1)c1ccccc1.COc1cc(OC)cc(OC)c1.C(=C\c1ccccc1)/c1ccccc1

Participants

10

Reactant 2

HCID 7501StyreneHCID 548641Phenyl Trifluoromethanesulfonate

Product 3

HCID 107401,1-DiphenylethyleneHCID 693011,3,5-TrimethoxybenzeneHCID 638088trans-Stilbene

Reagents, catalysts & solvents 5

HCID 8471TriethylamineReagentHCID 27342111,3-Bis(2,4,6-trimethylphenyl)imidazolium chlorideCatalystHCID 23665647Potassium tert-butoxideCatalystHCID 6228DimethylformamideSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-e4e693bc0f5f4bfc8826081a4308a820
Source dataset
Styrene Mizoroki-Heck

Reaction notes

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