Sodium ion → (RS)-1-(2-azido-propyl)-5-chloro-1,4-dihydro-indeno[1,2-b]pyrrole

HRID 684542Notes

Reaction equation

[CH2:23]([N:24]([CH2:25][CH3:26])[CH2:27][CH3:28])[CH3:29].[CH3:1][S:2](=[O:3])(=[O:4])[Cl:5].[CH3:37][N:38]([CH3:39])[CH:40]=[O:41].[Cl:34][CH2:35][Cl:36].[Cl:6][c:7]1[c:8]2[c:19]([cH:20][cH:21][cH:22]1)-[c:11]1[c:10]([cH:14][cH:13][n:12]1[CH2:15][CH:16]([CH3:17])[OH:18])[CH2:9]2.[N-:31]=[N+:32]=[N-:33].[Na+:30].[OH2:42]>>[Cl:6][c:7]1[c:8]2[c:19]([cH:20][cH:21][cH:22]1)-[c:11]1[c:10]([cH:14][cH:13][n:12]1[CH2:15][CH:16]([CH3:17])[N:31]=[N+:32]=[N-:33])[CH2:9]2

Participants

Reactant 8

HCID 923Sodium ion

HCID 962Water

HCID 6228Dimethylformamide

HCID 6344Dichloromethane

HCID 8471Triethylamine

HCID 31297Methanesulfonyl chloride

HCID 33558Azide

HCID 19036567(RS)-1-(5-chloro-1,4-dihydro-indeno[1,2-b]pyrrol-1-yl)-propan-2-ol

Product 1

HCID 19036562(RS)-1-(2-azido-propyl)-5-chloro-1,4-dihydro-indeno[1,2-b]pyrrole

Sources & evidence

ORD record: ord-3803b11cdaf345e980a1cff446a0e960
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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