Acetonitrile → 2-(2,3-dihydro-1H-inden-2-yl)acetaldehyde

HRID 687727Notes

Reaction equation

HRID 687727 reaction equation
[Al+3:15].[CH2:1]1[CH:2]([CH2:10][C:11](=[O:12])[OH:13])[CH2:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21.[CH2:20]1[c:21]2[c:22]([cH:23][cH:24][cH:25][cH:26]2)[CH2:27][CH:28]1[CH2:29][CH2:30][OH:31].[CH2:40]1[O:41][CH2:42][CH2:43][CH2:44]1.[CH3:32][N+:33]1([O-:34])[CH2:35][CH2:36][O:37][CH2:38][CH2:39]1.[CH3:48][C:49]#[N:50].[CH3:51][CH2:52][CH2:53][N+:54]([CH2:55][CH2:56][CH3:57])([CH2:58][CH2:59][CH3:60])[CH2:61][CH2:62][CH3:63].[Cl:45][CH2:46][Cl:47].[H-:14].[H-:17].[H-:18].[H-:19].[Li+:16].[O:64]=[Ru:65](=[O:66])([O-:67])=[O:68]>>[CH2:1]1[CH:2]([CH2:10][CH:11]=[O:12])[CH2:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21

Participants

12

Reactant 11

HCID 6342AcetonitrileHCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 9559TetrapropylammoniumHCID 28486Lithium ionHCID 82029Methyl morpholine oxideHCID 104727Aluminum CationHCID 166653Hydride4×HCID 51749552-(2,3-dihydro-1H-inden-2-yl)acetic AcidHCID 103520002-(2,3-dihydro-1H-inden-2-yl)ethanolHCID 178527104HCID 178527104, compound

Product 1

HCID 113786562-(2,3-dihydro-1H-inden-2-yl)acetaldehyde

Sources & evidence

ORD record
ord-ee4af22dc78f481bb0ed57c6eed1e92a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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