Chloride → Borane

HRID 693080Notes

Reaction equation

HRID 693080 reaction equation
[Al+3:38].[BH4-:5].[C:7]([CH3:8])([CH3:9])([CH3:10])[c:11]1[cH:12][c:13]([PH:21]([c:22]2[cH:23][c:24]([C:32]([CH3:33])([CH3:34])[CH3:35])[cH:25][c:26]([C:28]([CH3:29])([CH3:30])[CH3:31])[cH:27]2)=[O:36])[cH:14][c:15]([C:17]([CH3:18])([CH3:19])[CH3:20])[cH:16]1.[CH2:43]1[O:44][CH2:45][CH2:46][CH2:47]1.[CH3:49][c:50]1[cH:51][cH:52][cH:53][cH:54][cH:55]1.[Ce+3:2].[Cl-:1].[Cl-:3].[Cl-:4].[H-:37].[H-:40].[H-:41].[H-:42].[Li+:39].[Na+:6].[OH2:48]>>[BH3:5].[C:7]([CH3:8])([CH3:9])([CH3:10])[c:11]1[cH:12][c:13]([PH:21][c:22]2[cH:23][c:24]([C:32]([CH3:33])([CH3:34])[CH3:35])[cH:25][c:26]([C:28]([CH3:29])([CH3:30])[CH3:31])[cH:27]2)[cH:14][c:15]([C:17]([CH3:18])([CH3:19])[CH3:20])[cH:16]1

Participants

13

Reactant 11

HCID 312Chloride3×HCID 923Sodium ionHCID 962WaterHCID 1140TolueneHCID 8028TetrahydrofuranHCID 28123BorohydrideHCID 28486Lithium ionHCID 104727Aluminum CationHCID 114853Cerium(3+)HCID 166653Hydride4×HCID 178441221HCID 178441221, compound

Product 2

HCID 6331BoraneHCID 4191558BIS(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINE

Sources & evidence

ORD record
ord-c173b36175194332952c80df35efa6b9
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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