HRID697439

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID1068

Dimethyl sulfide

C2H6S

HCID8028

Tetrahydrofuran

C4H8O

HCID12335

Pentane, 1-iodo-

C5H11I

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID24611

Copper bromide (CuBr2)

Br2Cu

结构：CC(C)(C)[Si](OCc1ccc([Mg+])cc1Cl)(c1ccccc1)c1ccccc1

HCID178455508

未命名化合物

PRODUCTS

生成物

结构：CCCCCc1ccc(CO[Si](c2ccccc2)(c2ccccc2)C(C)(C)C)c(Cl)c1

HCID22388382

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7bc566cc624e4dd597fc49c60036440c
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (3/10)

反应 SMILES

[Br-:7].[C:8]([CH3:9])([CH3:10])([CH3:11])[Si:12]([O:13][CH2:14][c:15]1[c:16]([Cl:22])[cH:17][c:18]([Mg+:21])[cH:19][cH:20]1)([c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1)[c:29]1[cH:30][cH:31][cH:32][cH:33][cH:34]1.[CH3:35][N:36]([CH3:37])[P:38](=[O:39])([N:40]([CH3:41])[CH3:42])[N:43]([CH3:44])[CH3:45].[CH3:51][S:52][CH3:53].[Cu:54]([Br:55])[Br:56].[I:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[O:46]1[CH2:47][CH2:48][CH2:49][CH2:50]1>>[CH2:2]([CH2:3][CH2:4][CH2:5][CH3:6])[c:18]1[cH:17][c:16]([Cl:22])[c:15]([CH2:14][O:13][Si:12]([C:8]([CH3:9])([CH3:10])[CH3:11])([c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)[c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)[cH:20][cH:19]1