Sodium ion → (RS)-1-(2-azido-propyl)-1,4-dihydro-[1]benzothiopyrano[4,3-b]pyrrole

HRID 701036Notes

Reaction equation

HRID 701036 reaction equation
[CH3:1][S:2](=[O:3])(=[O:4])[Cl:5].[CH3:23][CH2:24][N:25]([CH2:26][CH3:27])[CH2:28][CH3:29].[CH3:37][CH2:38][O:39][CH2:40][CH3:41].[CH3:42][N:43]([CH3:44])[CH:45]=[O:46].[Cl:34][CH2:35][Cl:36].[N-:31]=[N+:32]=[N-:33].[Na+:30].[OH2:47].[n:6]1([CH2:19][CH:20]([CH3:21])[OH:22])[c:7]2[c:8]([cH:9][cH:10]1)[CH2:11][S:12][c:13]1[c:14]-2[cH:15][cH:16][cH:17][cH:18]1>>[n:6]1([CH2:19][CH:20]([CH3:21])[N:31]=[N+:32]=[N-:33])[c:7]2[c:8]([cH:9][cH:10]1)[CH2:11][S:12][c:13]1[c:14]-2[cH:15][cH:16][cH:17][cH:18]1

Participants

10

Reactant 9

HCID 923Sodium ionHCID 962WaterHCID 3283Diethyl EtherHCID 6228DimethylformamideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 31297Methanesulfonyl chlorideHCID 33558AzideHCID 19036598(RS)-1-(1,4-dihydro-[1]benzothiopyrano[4,3-b]pyrrol-1-yl)-propan-2-ol

Product 1

HCID 19036425(RS)-1-(2-azido-propyl)-1,4-dihydro-[1]benzothiopyrano[4,3-b]pyrrole

Sources & evidence

ORD record
ord-e666f56c1c2d47df8fdaf30c83ded4e2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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