HRID728520
反应详情
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实验过程
According to a method reported by Sieglitz and Marx, Berichte 56, 1619(1923) and by F. H. C. Stuart, Australian J. Chem., 478(1960), 8.2 g of 9-benzyl-anthracene was synthesized from 18.9 g of anthrone and 50 g of benzyl bromide. A solution of 4.8 g of 9-benzyl bromide in 40 ml of acetic acid was chloromethylated with 3.2 g of paraformaldehyde and hydrochloride gas to give 3.4 g of 9-benzyl-10-chloromethylanthracene (mp: 146° to 147° C.) after recrystallization from benzene.