Ammonia → HCID 178493057, compound

HRID 729196Notes

Reaction equation

HRID 729196 reaction equation
[NH2:1][C:2]1[C:3](=[O:15])[N:4]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[N:5]([CH3:8])[C:6]=1[CH3:7].[CH3:16][O:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[OH:24].N>O.CC(O)C.[Fe-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]>[CH3:16][O:17][C:18]1[C:19](=[O:24])[CH:20]=[CH:21]/[C:22](=[N:1]\[C:2]2[C:3](=[O:15])[N:4]([C:9]3[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=3)[N:5]([CH3:8])[C:6]=2[CH3:7])/[CH:23]=1

Participants

7

Reactant 3

HCID 222AmmoniaHCID 460GuaiacolHCID 21514-Aminoantipyrine

Product 1

HCID 178493057HCID 178493057, compound

Reagents, catalysts & solvents 3

HCID 178511488HCID 178511488, compoundCatalystHCID 962WaterSolventHCID 3776IsopropanolSolvent

Procedure

10 mmol of 4-amino-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one was dissolved in 30 ml of water. This solution was admixed with 10 mmol of 2-methoxyphenol in solution in 30 ml of 2-propanol, 3 ml of 20% aqueous ammonia and 22 mmol of potassium ferricyanide at a temperature ranging from 5 to 10° C.

Workup

  1. customranging from 5 to 10° C.

Sources & evidence

ORD record
ord-6ae651f3700344ee918e6d20364f3054
Source dataset
uspto-grants-2009_09
Patent number
US07582123B2

Reaction notes

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