Hydrochloric Acid → 9-Borabicyclo[3.3.1]nonane, 9-chloro-

HRID 741530Notes

Reaction equation

HRID 741530 reaction equation
[CH:1]12[BH:9][CH:5]([CH2:6][CH2:7][CH2:8]1)[CH2:4][CH2:3][CH2:2]2.[ClH:10]>CCOCC.CCCCCC>[Cl:10][B:9]1[CH:5]2[CH2:6][CH2:7][CH2:8][CH:1]1[CH2:2][CH2:3][CH2:4]2

Participants

5

Reactant 2

HCID 313Hydrochloric AcidHCID 789669-Borabicyclo(3.3.1)nonane

Product 1

HCID 109098229-Borabicyclo[3.3.1]nonane, 9-chloro-Yield 75%

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

The title compound was prepared in 75% yield following the method of Example 1 by treating 9-borabicyclo[3.3.1]nonane (9-BBN, Aldrich Chemical Company, Inc., Milwaukee, Wis.) with anhydrous HCl in ether. 11B NMR δ 79 ppm in hexane, bp 65° C. (0.3 mm).

Sources & evidence

ORD record
ord-9595334a782f420e929bf7c210e29da7
Source dataset
uspto-grants-1996_09
Patent number
US05552081

Reaction notes

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