Sodium hydride → HCID 73877107, compound

HRID 749565Notes

Reaction equation

HRID 749565 reaction equation
[C:1]([C:3]1[CH:14]=[CH:13][C:6]([CH2:7][CH:8]([C:11]#[N:12])[C:9]#[N:10])=[CH:5][CH:4]=1)#[N:2].[H-].[Na+].Cl[CH:18]=[CH:19][CH:20]([Cl:22])[Cl:21]>CN(C)C=O>[C:1]([C:3]1[CH:14]=[CH:13][C:6]([CH2:7][C:8]([CH:18]=[CH:19][CH:20]([Cl:22])[Cl:21])([C:11]#[N:12])[C:9]#[N:10])=[CH:5][CH:4]=1)#[N:2]

Participants

5

Reactant 3

HCID 24758Sodium hydrideHCID 1178191-Propene, 1,3,3-trichloro-HCID 11286827HCID 11286827, compound

Product 1

HCID 73877107HCID 73877107, compoundYield 34.1%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Using 0.37 g of (4-cyanobenzyl)malononitrile, 5 ml of N,N-dimethylformamide, 0.12 g of sodium hydride (60% in oil), and 0.25 g of 1,3,3-trichloropropene, and according to the process described in the Production Example 1, there was obtained 0.17 g of 2-(4-cyanobenzyl)-2-(3,3-dichloropropenyl)malononitrile (the present compound (56)).

Sources & evidence

ORD record
ord-09504706476346d3a7a3bdbe91368c5c
Source dataset
uspto-grants-2008_07
Patent number
US07402691B2

Reaction notes

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