Dimethylformamide → (4-tert-Butyl-2-nitro-phenylethynyl)-trimethyl-silane

HRID 798898Notes

Reaction equation

HRID 798898 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[c:5]1[cH:6][c:7]([N+:19](=[O:20])[O-:21])[c:8]([O:11][S:12]([C:13]([F:14])([F:15])[F:16])(=[O:17])=[O:18])[cH:9][cH:10]1.[CH3:23][CH2:24][N:25]([CH2:26][CH3:27])[CH2:28][CH3:29].[CH3:30][Si:31]([CH3:32])([CH3:33])[C:34]#[CH:35].[CH3:36][N:37]([CH3:38])[CH:39]=[O:40].[I-:22]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[c:5]1[cH:6][c:7]([N+:19](=[O:20])[O-:21])[c:8]([C:35]#[C:34][Si:31]([CH3:30])([CH3:32])[CH3:33])[cH:9][cH:10]1

Participants

6

Reactant 5

HCID 6228DimethylformamideHCID 8471TriethylamineHCID 30165Iodide IonHCID 66111TrimethylsilylacetyleneHCID 231090154-tert-Butyl-2-nitrophenyl trifluoromethanesulfonate

Product 1

HCID 58016188(4-tert-Butyl-2-nitro-phenylethynyl)-trimethyl-silane

Sources & evidence

ORD record
ord-f44f619da52e4d8e9357bc644fb06cc5
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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