Acetate → 4-ethyl-8-methoxy-1H-pyrano[3,4-c]pyridine
Reaction equation
[C:16](=[O:17])([O-:18])[O-:19].[CH2:1]([CH:2]=[CH:3][CH3:4])[O:5][CH2:6][c:7]1[c:8]([O:14][CH3:15])[n:9][cH:10][cH:11][c:12]1[I:13].[CH3:23][CH2:24][CH2:25][CH2:26][N+:27]([CH2:28][CH2:29][CH2:30][CH3:31])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39].[CH3:40][N:41]([CH3:42])[CH:43]=[O:44].[Cl-:22].[K+:20].[K+:21].[O-:46][C:47]([CH3:48])=[O:49].[O-:50][C:51]([CH3:52])=[O:53].[Pd+2:45].[Rh:54][Cl:55].[c:56]1([P:57]([c:58]2[cH:59][cH:60][cH:61][cH:62][cH:63]2)[c:64]2[cH:65][cH:66][cH:67][cH:68][cH:69]2)[cH:70][cH:71][cH:72][cH:73][cH:74]1.[c:75]1([P:76]([c:77]2[cH:78][cH:79][cH:80][cH:81][cH:82]2)[c:83]2[cH:84][cH:85][cH:86][cH:87][cH:88]2)[cH:89][cH:90][cH:91][cH:92][cH:93]1.[c:94]1([P:95]([c:96]2[cH:97][cH:98][cH:99][cH:100][cH:101]2)[c:102]2[cH:103][cH:104][cH:105][cH:106][cH:107]2)[cH:108][cH:109][cH:110][cH:111][cH:112]1>>[CH:1]1=[C:2]([CH2:3][CH3:4])[c:12]2[c:7]([c:8]([O:14][CH3:15])[n:9][cH:10][cH:11]2)[CH2:6][O:5]1Participants
11
Reactant 10
HCID 175Acetate2×
HCID 312Chloride
HCID 813Potassium Cation2×
HCID 6228Dimethylformamide
HCID 11776Triphenylphosphine3×
HCID 16028Tetrabutylammonium
HCID 19660Carbonate Ion
HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)
HCID 544155093-(But-2-enyloxymethyl)-4-iodo-2-methoxypyridine
HCID 178479812HCID 178479812, compoundProduct 1
Sources & evidence
- ORD record
- ord-bd23d6c80ce44b92a1b9ec6fc87deee7
- Source dataset
- Test data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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