Chloride → 4-[2-Benzyloxy-5-(5-methyl-7-nitroindan-4-yloxy)benzylidene]tetrahydropyran

HRID 806957Notes

Reaction equation

HRID 806957 reaction equation
[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[O:9][c:10]1[c:11]([CH2:12][P+:13]([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:32][c:33]([O:36][c:37]2[c:38]3[c:42]([c:43]([N+:47](=[O:48])[O-:49])[cH:44][c:45]2[CH3:46])[CH2:41][CH2:40][CH2:39]3)[cH:34][cH:35]1.[CH3:60][S:61]([CH3:62])=[O:63].[Cl-:1].[ClH:59].[H-:50].[Na+:51].[O:52]1[CH2:53][CH2:54][C:55](=[O:58])[CH2:56][CH2:57]1>>[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[O:9][c:10]1[c:11]([CH:12]=[C:55]2[CH2:54][CH2:53][O:52][CH2:57][CH2:56]2)[cH:32][c:33]([O:36][c:37]2[c:38]3[c:42]([c:43]([N+:47](=[O:48])[O-:49])[cH:44][c:45]2[CH3:46])[CH2:41][CH2:40][CH2:39]3)[cH:34][cH:35]1

Participants

8

Reactant 7

HCID 312ChlorideHCID 313Hydrochloric AcidHCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 121599Tetrahydro-4H-pyran-4-oneHCID 166653HydrideHCID 21110567[5-[(5-methyl-7-nitro-2,3-dihydro-1H-inden-4-yl)oxy]-2-phenylmethoxyphenyl]methyl-triphenylphosphanium

Product 1

HCID 211105754-[2-Benzyloxy-5-(5-methyl-7-nitroindan-4-yloxy)benzylidene]tetrahydropyran

Sources & evidence

ORD record
ord-eef0f19c2b7d4de6a61d76ca6cc0a1a1
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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