Bicarbonate Ion → 3-(Furan-2-yl)-acryloyl azide

HRID 807021Notes

Reaction equation

HRID 807021 reaction equation
[C:35](=[O:36])([O-:37])[OH:38].[CH3:11][CH2:12][N:13]([CH2:14][CH3:15])[CH2:16][CH3:17].[CH3:45][CH2:46][O:47][C:48](=[O:49])[CH3:50].[Na+:39].[O:40]1[CH2:41][CH2:42][CH2:43][CH2:44]1.[c:18]1([P:19]([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)(=[O:26])[N:32]=[N+:33]=[N-:34])[cH:27][cH:28][cH:29][cH:30][cH:31]1.[o:1]1[c:2]([CH:6]=[CH:7][C:8](=[O:9])[OH:10])[cH:3][cH:4][cH:5]1>>[o:1]1[c:2]([CH:6]=[CH:7][C:8](=[O:10])[N:32]=[N+:33]=[N-:34])[cH:3][cH:4][cH:5]1

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 8857Ethyl AcetateHCID 10876Furylacrylic acidHCID 199401P,P-Diphenylphosphinic azide

Product 1

HCID 27775243-(Furan-2-yl)-acryloyl azide

Sources & evidence

ORD record
ord-7c6c471d78a445f6baadf5f05d0f59ab
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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