Ammonium → 2-(1,1-Diethyl-propyl)-malonic acid dimethyl ester

HRID 809283Notes

Reaction equation

HRID 809283 reaction equation
[CH3:1][CH2:2][Mg:3][Cl:4].[CH3:5][O:6][C:7]([C:8]([C:9](=[O:10])[O:11][CH3:12])=[C:13]([CH2:14][CH3:15])[CH2:16][CH3:17])=[O:18].[Cl-:19].[Cu:26][I:27].[NH4+:20].[O:21]1[CH2:22][CH2:23][CH2:24][CH2:25]1>>[CH3:1][CH2:2][C:13]([CH:8]([C:7]([O:6][CH3:5])=[O:18])[C:9](=[O:10])[O:11][CH3:12])([CH2:14][CH3:15])[CH2:16][CH3:17]

Participants

7

Reactant 6

HCID 223AmmoniumHCID 312ChlorideHCID 8028TetrahydrofuranHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 856487702-(1-Ethyl-propylidene)-malonic acid dimethyl esterHCID 178461633HCID 178461633, compound

Product 1

HCID 866403882-(1,1-Diethyl-propyl)-malonic acid dimethyl ester

Sources & evidence

ORD record
ord-410a5e84223f4328a1d2cd11c38c830c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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