Acetate → 3-(3-Oxo-3-ethoxy-1-propenyl)benzoic acid

HRID 811142Notes

Reaction equation

HRID 811142 reaction equation
[C:11]([CH:12]=[CH2:13])(=[O:14])[O:15][CH2:16][CH3:17].[C:30]([O-:31])(=[O:32])[CH3:33].[C:35]([O-:36])(=[O:37])[CH3:38].[CH3:18][CH2:19][N:20]([CH2:21][CH3:22])[CH2:23][CH3:24].[I:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][cH:9][cH:10]1.[O:25]=[CH:26][N:27]([CH3:28])[CH3:29].[Pd+2:34]>>[c:2]1([CH:13]=[CH:12][C:11](=[O:14])[O:15][CH2:16][CH3:17])[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][cH:9][cH:10]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6228DimethylformamideHCID 8471TriethylamineHCID 8821Ethyl AcrylateHCID 120603-Iodobenzoic acidHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 534171853-(3-Oxo-3-ethoxy-1-propenyl)benzoic acid

Sources & evidence

ORD record
ord-c71ee3cc2c2140249c9e8d85cc1ea9e6
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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