Acetate → 2-(Thiophen-2-yl)-N-(2,4,4-trimethylpentan-2-yl)ethene-1-sulfonamide

HRID 812370Notes

Reaction equation

HRID 812370 reaction equation
[Br:34][c:35]1[s:36][cH:37][cH:38][cH:39]1.[C:52]([O-:53])(=[O:54])[CH3:55].[C:57]([O-:58])(=[O:59])[CH3:60].[CH3:20][C:21]([CH2:22][C:23]([CH3:24])([CH3:25])[CH3:26])([CH3:27])[NH:28][S:29](=[O:30])(=[O:31])[CH:32]=[CH2:33].[CH3:40][CH2:41][N:42]([CH2:43][CH3:44])[CH2:45][CH3:46].[CH3:47][N:48]([CH3:49])[CH:50]=[O:51].[Pd+2:56].[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[CH3:20][C:21]([CH2:22][C:23]([CH3:24])([CH3:25])[CH3:26])([CH3:27])[NH:28][S:29](=[O:30])(=[O:31])[CH:32]=[CH:33][c:35]1[s:36][cH:37][cH:38][cH:39]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6228DimethylformamideHCID 8471TriethylamineHCID 11776TriphenylphosphineHCID 138512-BromothiopheneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 17748074N-(2,4,4-Trimethylpentan-2-yl)ethenesulfonamide

Product 1

HCID 714266792-(Thiophen-2-yl)-N-(2,4,4-trimethylpentan-2-yl)ethene-1-sulfonamide

Sources & evidence

ORD record
ord-4dae6fd67a804a0cb57397ceee713bd4
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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