Chloride → 6-Bromo-4-tert-butyl-1,1-dimethyl-1,2-dihydronaphthalene

HRID 829967Notes

Reaction equation

HRID 829967 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:10]([cH:11]1)[C:9](=[O:12])[CH2:8][CH2:7][C:6]2([CH3:13])[CH3:14].[C:16]([CH3:17])([CH3:18])([CH3:19])[Mg+:20].[Cl-:15].[O:32]1[CH2:33][CH2:34][CH2:35][CH2:36]1.[c:21]1([CH3:22])[cH:23][cH:24][c:25]([S:26]([OH:27])(=[O:28])=[O:29])[cH:30][cH:31]1>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:10]([cH:11]1)[C:9]([C:16]([CH3:17])([CH3:18])[CH3:19])=[CH:8][CH2:7][C:6]2([CH3:13])[CH3:14]

Participants

6

Reactant 5

HCID 312ChlorideHCID 6101p-Toluenesulfonic acidHCID 8028TetrahydrofuranHCID 107533577-Bromo-4,4-dimethyl-1,2,3,4-tetrahydronaphthalen-1-oneHCID 178448412HCID 178448412, compound

Product 1

HCID 158960196-Bromo-4-tert-butyl-1,1-dimethyl-1,2-dihydronaphthalene

Sources & evidence

ORD record
ord-e44c05303a804b52ab3b62b9017a5585
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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