Ammonium → 6-(3-bromophenyl)-1,4,4-trimethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one

HRID 836092Notes

Reaction equation

HRID 836092 reaction equation
[Br:1][c:2]1[cH:3][c:4](-[c:8]2[cH:9][cH:10][c:11]3[c:12]([cH:20]2)[C:13]([CH3:18])([CH3:19])[O:14][C:15](=[O:17])[NH:16]3)[cH:5][cH:6][cH:7]1.[CH3:37][CH2:38][O:39][C:40](=[O:41])[CH3:42].[H-:21].[I:23][CH3:24].[NH4+:25].[NH4+:26].[Na+:22].[O-:27][S:28](=[O:29])(=[O:30])[O-:31].[O:32]=[CH:33][N:34]([CH3:35])[CH3:36]>>[Br:1][c:2]1[cH:3][c:4](-[c:8]2[cH:9][cH:10][c:11]3[c:12]([cH:20]2)[C:13]([CH3:18])([CH3:19])[O:14][C:15](=[O:17])[N:16]3[CH3:24])[cH:5][cH:6][cH:7]1

Participants

9

Reactant 8

HCID 223Ammonium2×HCID 923Sodium ionHCID 1117Sulfate IonHCID 6228DimethylformamideHCID 6328Methyl iodideHCID 8857Ethyl AcetateHCID 166653HydrideHCID 98624116-(3-Bromo-phenyl)-4,4-dimethyl-1,4-dihydro-benzo[d][1,3]oxazin-2-one

Product 1

HCID 235095946-(3-bromophenyl)-1,4,4-trimethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one

Sources & evidence

ORD record
ord-05f8c7bea2a547609d9b2c87f15d1443
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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