Chloride → 4,5-Difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole

HRID 836171Notes

Reaction equation

HRID 836171 reaction equation
[Al+3:2].[Cl-:24].[Cl-:25].[Cl-:26].[Cl-:27].[Cl:7][C:8]1([F:23])[O:9][C:10]([C:15]([F:16])([F:17])[F:18])([C:19]([F:20])([F:21])[F:22])[O:11][C:12]1([F:13])[Cl:14].[H-:1].[H-:4].[H-:5].[H-:6].[Li+:3].[O:29]1[CH2:30][CH2:31][CH2:32][CH2:33]1.[Ti+4:28]>>[C:8]1([F:23])=[C:12]([F:13])[O:11][C:10]([C:15]([F:16])([F:17])[F:18])([C:19]([F:20])([F:21])[F:22])[O:9]1

Participants

8

Reactant 7

HCID 312Chloride4×HCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 114942Titanium cation (4+)HCID 1629194,5-Dichloro-4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxolaneHCID 166653Hydride4×

Product 1

HCID 1699574,5-Difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole

Sources & evidence

ORD record
ord-206c6c5e35fd4eabb9631bc95520e60c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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