Azobisisobutyronitrile → HCID 86596289, compound

HRID 900639Notes

Reaction equation

HRID 900639 reaction equation
C(OC(C)COC)(=O)C.[C:10]([O-:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:21][CH2:22][CH2:23][OH:24])(=[O:20])[C:17]([CH3:19])=[CH2:18].[C:25]([O:29][C:30](=[O:33])[CH:31]=[CH2:32])([CH3:28])([CH3:27])[CH3:26].[C:34]([OH:38])(=[O:37])[CH:35]=[CH2:36].CC(N=NC(C#N)(C)C)(C#N)C>>[C:10]([O-:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:21][CH2:22][CH2:23][OH:24])(=[O:20])[C:17]([CH3:19])=[CH2:18].[C:25]([O:29][C:30](=[O:33])[CH:31]=[CH2:32])([CH3:28])([CH3:27])[CH3:26].[C:34]([OH:38])(=[O:37])[CH:35]=[CH2:36]

Participants

7

Reactant 6

HCID 6547AzobisisobutyronitrileHCID 6581Acrylic AcidHCID 7946Propylene glycol methyl ether acetateHCID 133602-Hydroxyethyl MethacrylateHCID 15458tert-Butyl acrylateHCID 87595Methacrylate

Product 1

HCID 86596289HCID 86596289, compoundYield 88%

Procedure

To 50 g of propylene glycol methyl ether acetate (PGMEA) were added 5 g of 9-anthracenemethyl methacrylate, 1 g of 2-hydroxyethyl methacrylate, 3 g of t-butylacrylate, 1 g of acrylic acid and 0.4 g of AIBN. The prepared solution was reacted at 66° C. for 8 hours. After the reaction, the resulting mixture was precipitated in ethyl ether, filtered, and dried under vacuum condition, thereby obtaining poly(9-anthracenemethyl methacrylate/2-hydroxyethyl methacrylate/t-butylacrylate/acrylic acid) having a molecular weight of 12,500 (yield: 88%) (see the NMR spectrum of FIG. 1).

Workup

  1. customThe prepared solution was reacted at 66° C. for 8 hours
  2. customAfter the reaction
  3. customthe resulting mixture was precipitated in ethyl ether
  4. filtrationfiltered
  5. customdried under vacuum condition

Sources & evidence

ORD record
ord-dbce1ccd94724d1d8199b816cd9170d4
Source dataset
uspto-grants-2008_04
Patent number
US07361447B2

Reaction notes

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