Azobisisobutyronitrile → HCID 86596290, compound

HRID 900640Notes

Reaction equation

HRID 900640 reaction equation
CC(OC(C)=O)COC.[C:10]([O-:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:20][C:21](=[O:24])[CH:22]=[CH2:23])([CH3:19])([CH3:18])[CH3:17].[C:25]([OH:29])(=[O:28])[CH:26]=[CH2:27].CC(N=NC(C#N)(C)C)(C#N)C>>[C:10]([O-:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:20][C:21](=[O:24])[CH:22]=[CH2:23])([CH3:19])([CH3:18])[CH3:17].[C:25]([OH:29])(=[O:28])[CH:26]=[CH2:27]

Participants

6

Reactant 5

HCID 6547AzobisisobutyronitrileHCID 6581Acrylic AcidHCID 7946Propylene glycol methyl ether acetateHCID 15458tert-Butyl acrylateHCID 87595Methacrylate

Product 1

HCID 86596290HCID 86596290, compoundYield 80%

Procedure

To 50 g of PGMEA were added 6 g of 9-anthracenemethyl methacrylate, 3 g of t-butylacrylate, 1 g of acrylic acid and 0.8 g of AIBN. The prepared solution was reacted at 66° C. for 8 hours. After the reaction, the resulting mixture was precipitated in ethyl ether, filtered, and dried under vacuum condition thereby obtaining poly(9-anthracenemethyl methacrylate/t-butylacrylate/acrylic acid) having a molecular weight of 11,200 (yield: 80%) (see the NMR spectrum of FIG. 2).

Workup

  1. customThe prepared solution was reacted at 66° C. for 8 hours
  2. customAfter the reaction
  3. customthe resulting mixture was precipitated in ethyl ether
  4. filtrationfiltered
  5. customdried under vacuum condition

Sources & evidence

ORD record
ord-f1beee3ba558418d97e68d0687ba65d3
Source dataset
uspto-grants-2008_04
Patent number
US07361447B2

Reaction notes

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