Butyl vinyl ether → Biphenyl

HRID 914566Notes

Reaction equation

HRID 914566 reaction equation
C=COCCCC.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=S(=O)(Oc1ccccc1)C(F)(F)F.[Pd].[Pd]>CC(C)(C)P1CN(c2ccc(C(F)(F)F)cc2)CP(C(C)(C)C)CN(c2ccc(C(F)(F)F)cc2)C1.CCN(CC)CC.Cc1ccccc1>C=C(OCCCC)c1ccccc1.CCCCO/C=C/c1ccccc1.CCCCO/C=C\c1ccccc1.c1ccc(-c2ccccc2)cc1

Participants

11

Reactant 2

HCID 8108Butyl vinyl etherHCID 548641Phenyl Trifluoromethanesulfonate

Product 5

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 10464845(1-Butoxyethenyl)benzeneHCID 10464846HCID 10464846, compoundHCID 13834617HCID 13834617, compound

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 1778483303,7-Di-tert-butyl-1,5-bis(4-(trifluoromethyl)phenyl)-1,5,3,7-diazadiphosphocaneCatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-5a76c550155f4526acee52644878bec9
Source dataset
Vinyl ether Mizoroki-Heck

Reaction notes

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