Water → Ethyl 4-((trimethylsilyl)ethynyl)benzoate

HRID 932643Notes

Reaction equation

HRID 932643 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([C:6](=[O:7])[O:8][CH2:9][CH3:10])[cH:11][cH:12]1.[CH2:19]([NH:20][CH2:21][CH3:22])[CH3:23].[CH3:13][Si:14]([CH3:15])([CH3:16])[C:17]#[CH:18].[Cu:24][I:25].[OH2:26]>>[c:2]1([C:18]#[C:17][Si:14]([CH3:13])([CH3:15])[CH3:16])[cH:3][cH:4][c:5]([C:6](=[O:7])[O:8][CH2:9][CH3:10])[cH:11][cH:12]1

Participants

6

Reactant 5

HCID 962WaterHCID 8021DiethylamineHCID 22043Ethyl 4-bromobenzoateHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111Trimethylsilylacetylene

Product 1

HCID 10729134Ethyl 4-((trimethylsilyl)ethynyl)benzoate

Sources & evidence

ORD record
ord-720f7f3d7c7e48e38454810e61919e3a
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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