Acetone → 6-Bromo-2,2-dimethyl-4H-benzo[d][1,3]dioxine

HRID 933496Notes

Reaction equation

HRID 933496 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([OH:10])[c:6]([CH2:7][OH:8])[cH:9]1.[CH3:11][C:12]([CH3:13])=[O:14].[CH3:17][CH2:18][O:19][CH2:20][CH3:21].[CH3:22][O:23][C:24]([O:25][CH3:26])([CH3:27])[CH3:28].[Cl-:29].[Cl-:31].[Na+:16].[OH-:15].[Zn+2:30]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([cH:9]1)[CH2:7][O:8][C:12]([CH3:11])([CH3:13])[O:10]2

Participants

9

Reactant 8

HCID 180AcetoneHCID 312Chloride2×HCID 923Sodium ionHCID 961HydroxideHCID 3283Diethyl EtherHCID 64952,2-DimethoxypropaneHCID 32051Zinc(2+)HCID 753425-Bromo-2-hydroxybenzyl alcohol

Product 1

HCID 145203386-Bromo-2,2-dimethyl-4H-benzo[d][1,3]dioxine

Sources & evidence

ORD record
ord-fb8dc30c762d4ed2a5a638a427b62c5b
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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