Chloride → 1-Methoxy-2,2,6,6-tetramethyl-piperidin-4-ol

HRID 935276Notes

Reaction equation

HRID 935276 reaction equation
[CH2:26]([Cl:27])[Cl:28].[CH3:15][S:16](=[O:17])[CH3:18].[Cl-:29].[Cl-:31].[Cl-:32].[ClH:25].[Na+:19].[Na+:20].[O-:21][C:22](=[O:23])[O-:24].[OH:13][OH:14].[OH:1][CH:2]1[CH2:3][C:4]([CH3:11])([CH3:12])[N:5]([OH:10])[C:6]([CH3:8])([CH3:9])[CH2:7]1.[Ti+3:30]>>[OH:1][CH:2]1[CH2:3][C:4]([CH3:11])([CH3:12])[N:5]([O:10][CH3:15])[C:6]([CH3:8])([CH3:9])[CH2:7]1

Participants

10

Reactant 9

HCID 312Chloride3×HCID 313Hydrochloric AcidHCID 679Dimethyl SulfoxideHCID 784Hydrogen PeroxideHCID 923Sodium ion2×HCID 53951,4-Dihydroxy-2,2,6,6-tetramethylpiperidineHCID 6344DichloromethaneHCID 19660Carbonate IonHCID 5153393TiIII

Product 1

HCID 109977701-Methoxy-2,2,6,6-tetramethyl-piperidin-4-ol

Sources & evidence

ORD record
ord-ef542dd8508d4b1d96afbe9dec9879a6
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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