Potassium Cation → (RS)-4-[1-(4-m-tolyl-butyl)-pyrrolidine-3-sulfonyl]-phenol

HRID 937753Notes

Reaction equation

HRID 937753 reaction equation
[Br:25][c:26]1[cH:27][c:28]([CH3:32])[cH:29][cH:30][cH:31]1.[CH2:1]([CH2:2][CH:3]=[CH2:4])[N:5]1[CH2:6][CH:7]([S:10](=[O:11])(=[O:12])[c:13]2[cH:14][cH:15][c:16]([OH:19])[cH:17][cH:18]2)[CH2:8][CH2:9]1.[CH2:39]1[O:40][CH2:41][CH2:42][CH2:43]1.[CH:44]12[CH2:45][CH2:46][CH2:47][CH:48]([BH:49]1)[CH2:50][CH2:51][CH2:52]2.[K+:33].[K+:34].[O-:35][C:36]([O-:37])=[O:38].[O:20]=[CH:21][N:22]([CH3:23])[CH3:24]>>[CH2:1]([CH2:2][CH2:3][CH2:4][c:26]1[cH:27][c:28]([CH3:32])[cH:29][cH:30][cH:31]1)[N:5]1[CH2:6][CH:7]([S:10](=[O:11])(=[O:12])[c:13]2[cH:14][cH:15][c:16]([OH:19])[cH:17][cH:18]2)[CH2:8][CH2:9]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 8028TetrahydrofuranHCID 115603-BromotolueneHCID 19660Carbonate IonHCID 789669-Borabicyclo(3.3.1)nonaneHCID 18425811(RS)-4-(1-but-3-enyl-pyrrolidine-3-sulfonyl)-phenol

Product 1

HCID 10292749(RS)-4-[1-(4-m-tolyl-butyl)-pyrrolidine-3-sulfonyl]-phenol

Sources & evidence

ORD record
ord-1fcc43a771fc426aabc5a7a7708bff7e
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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