Chloride → [6-[(2-acetyl-1-benzofuran-7-yl)oxy]-4,5-diacetyloxythian-3-yl] acetate

HRID 951525Notes

Reaction equation

HRID 951525 reaction equation
[C:1]([CH3:2])(=[O:3])[c:4]1[o:5][c:6]2[c:7]([cH:8]1)[cH:9][cH:10][cH:11][c:12]2[OH:13].[C:21]([CH3:22])(=[O:23])[O:24][CH:25]1[CH:26]([Br:39])[S:27][CH2:28][CH:29]([O:35][C:36]([CH3:37])=[O:38])[CH:30]1[O:31][C:32]([CH3:33])=[O:34].[CH3:14][c:15]1[cH:16][cH:17][cH:18][cH:19][cH:20]1.[CH3:45][CH2:46][N:47]([CH2:48][CH3:49])[CH2:50][CH3:51].[CH3:52][C:53]#[N:54].[Cl-:42].[Cl-:44].[Na+:41].[OH-:40].[Zn+2:43]>>[C:1]([CH3:2])(=[O:3])[c:4]1[o:5][c:6]2[c:7]([cH:8]1)[cH:9][cH:10][cH:11][c:12]2[O:13][CH:26]1[CH:25]([O:24][C:21]([CH3:22])=[O:23])[CH:30]([O:31][C:32]([CH3:33])=[O:34])[CH:29]([O:35][C:36]([CH3:37])=[O:38])[CH2:28][S:27]1

Participants

10

Reactant 9

HCID 312Chloride2×HCID 923Sodium ionHCID 961HydroxideHCID 1140TolueneHCID 6342AcetonitrileHCID 8471TriethylamineHCID 32051Zinc(2+)HCID 5953292-Acetyl-7-hydroxybenzofuranHCID 14374025(3S,4S,5R,6S)-4,5-bis(acetyloxy)-6-bromothian-3-yl acetate

Product 1

HCID 178475654[6-[(2-acetyl-1-benzofuran-7-yl)oxy]-4,5-diacetyloxythian-3-yl] acetate

Sources & evidence

ORD record
ord-076b4c97c81f46dd8fe9e634a5924b5a
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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