Hydrogen Sulfide → 6-tert-Butyl-2,4-dimethyl-3-(sulfanylmethyl)phenol

HRID 972085Notes

Reaction equation

HRID 972085 reaction equation
[CH3:1][C:2]1[C:7]([CH2:8]Cl)=[C:6]([CH3:10])[CH:5]=[C:4]([C:11]([CH3:14])([CH3:13])[CH3:12])[C:3]=1[OH:15].C(N(CC)CC)C.[SH2:23]>O1CCCC1>[CH3:1][C:2]1[C:7]([CH2:8][SH:23])=[C:6]([CH3:10])[CH:5]=[C:4]([C:11]([CH3:14])([CH3:13])[CH3:12])[C:3]=1[OH:15]

Participants

5

Reactant 3

HCID 402Hydrogen SulfideHCID 8471TriethylamineHCID 901316-tert-Butyl-3-(chloromethyl)-2,4-dimethylphenol

Product 1

HCID 205748096-tert-Butyl-2,4-dimethyl-3-(sulfanylmethyl)phenol

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

This material was synthesized according to the procedure of Song (Song, J. U.S. Pat. No. 3,810,929) using 2,4-dimethyl-3-chloromethyl-6-t-butylphenol (160.8 g, 0.71 m), triethylamine (80 g), tetrahydrofuran (200 ml) and excess hydrogen sulfide. This afforded upon work-up a slightly yellow odorous oil.

Workup

  1. customThis material was synthesized
  2. customThis afforded upon work-up a slightly yellow odorous oil

Sources & evidence

ORD record
ord-da0fe72c90f44c90815efb44cbb62490
Source dataset
uspto-grants-1979_07
Patent number
US04163008

Reaction notes

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