Hydrogen Peroxide → Hydrogen Peroxide

HRID 979745Notes

Reaction equation

HRID 979745 reaction equation
[C:1]([NH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18])(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[OH:20][OH:21]>CS(O)(=O)=O>[C:1]([NH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18])(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[OH:20][OH:21].[C:1]([NH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([O:19][OH:20])=[O:18])(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

6

Reactant 2

HCID 784Hydrogen PeroxideHCID 11022006Hexanoic acid, 6-[(1-oxononyl)amino]-

Product 3

HCID 784Hydrogen PeroxideHCID 11022006Hexanoic acid, 6-[(1-oxononyl)amino]-HCID 17979835HCID 17979835, compound

Reagents, catalysts & solvents 1

HCID 6395Methanesulfonic AcidSolvent2×

Procedure

N-nonanoyl-6-aminoperoxycaproic acid was prepared by reaction of N-nonanoyl-6-aminocaproic acid with hydrogen peroxide in 98% methanesulfonic acid according to the procedure described in Example II. From 103 g (0.381 mol) of N-nonanoyl-6-aminocaproic acid, 44 g (1.29 mol) of hydrogen peroxide, and 170 mL of methanesulfonic acid was obtained 74.2 g of N-nonanoyl-6-aminoperoxycaproic acid having a peroxyacid AvO of 5.31% and a mp of 60° C. (theoretical yield=109.5 g of 5.57% AvO).

Sources & evidence

ORD record
ord-5ddda3fa1c4b492094fe74216d8f180f
Source dataset
uspto-grants-1987_01
Patent number
US04634551

Reaction notes

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