Potassium Iodide → HCID 18329731, compound

HRID 981141Notes

Reaction equation

HRID 981141 reaction equation
[I:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[I-].[K+].[C:11](=[O:14])([O-])[O-].[K+].[K+].[CH3:17][C:18](CC(C)C)=O>>[I:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][CH2:17][CH2:18][O:14][CH3:11])=[CH:4][CH:3]=1

Participants

5

Reactant 4

HCID 4875Potassium IodideHCID 7909Methyl Isobutyl KetoneHCID 108944-IodophenolHCID 11430Potassium Carbonate

Product 1

HCID 18329731HCID 18329731, compound

Procedure

A mixture of 4-iodophenol (1.0 g) 1-bromo-2-methoxyethane (0.7 g), potassium iodide (0.83 g), potassium carbonate (0.7 g) and methyl isobutylketone (10 ml) was refluxed for 18 h, diluted with ER (50 ml), filtered and evaporated. The residue was distilled to give the title compound (0.83 g). T.l.c. (cyclohexane-ER 1:1) Rf 0.6

Workup

  1. temperaturewas refluxed for 18 h
  2. additiondiluted with ER (50 ml)
  3. filtrationfiltered
  4. customevaporated
  5. distillationThe residue was distilled

Sources & evidence

ORD record
ord-4588373aecbf45c290aab60b0b530111
Source dataset
uspto-grants-1991_02
Patent number
US04990505

Reaction notes

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