Methane → 1-Disiloxanol, 1,1,3,3,3-pentamethyl-, 1-acetate
Reaktionsgleichung
[CH3:1][Si:2]([CH3:8])([CH3:7])[O:3][SiH:4]([CH3:6])[CH3:5].[C:9]([O:12]CC=C)(=[O:11])[CH3:10].C>[Pd]>[CH3:1][Si:2]([CH3:8])([CH3:7])[O:3][Si:4]([CH3:6])([CH3:5])[O:12][C:9](=[O:11])[CH3:10]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 105 °C
Versuchsvorschrift
A mixture containing 14.8 g of 1,1,1,3,3-pentamethyldisiloxane, 10.0 g of allyl acetate (acetic acid allylester) and 0.01 g of palladium supported on activated charcoal, in which the 0.1 g refers to the total weight of the charcoal and the palladium, is heated to boiling under reflux (approximately 105° C.) for 4 hours. The 1,1,1,3,3-pentamethyl-3-acetoxydisiloxane yield is quantitative.
Quellen und Nachweise
- ORD-Eintrag
- ord-a176e21bb5f04f3c962418b03a0824fd
- Quelldatensatz
- uspto-grants-1987_07
- Patentnummer
- US04680365
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