Ammonia → Allylamine

HRID 2165975

Reaktionsgleichung

Reaktionsgleichung von HRID 2165975
C1(P(C2C=CC=CC=2)CCCCP(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(O)CCO.C(O)C=C.N.[CH2:41]([N:44](CC=C)[CH2:45][CH:46]=[CH2:47])[CH:42]=[CH2:43]>Cl[Pd]Cl.O>[CH2:41]([NH2:44])[CH:42]=[CH2:43].[CH2:41]([NH:44][CH2:45][CH:46]=[CH2:47])[CH:42]=[CH2:43]

Komponenten

9

Edukt 5

HCID 222AmmoniaHCID 7617TriallylamineHCID 7858Allyl AlcoholHCID 104421,3-PropanediolHCID 821241,4-Bis(diphenylphosphino)butane

Produkt 2

HCID 7853AllylamineHCID 31279Diallylamine

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 24290Palladium ChlorideKatalysatorHCID 962WaterLösungsmittel

Versuchsvorschrift

To 1.8 mg (0.01 millimole) of PdCl2 was added 8.5 mg (0.02 millimole) of 1,4-bis(diphenylphosphino)butane, and 5.0 g of 1,3-propane-diol and 3.6 g of water were added and reaction between 8.4 g (145 millimoles) of allyl alcohol and 3.2 g (188 millimoles) of ammonia was carried out at 110° C. with stirring for 2 hours. As the products, there were obtained 0.26 g (4.6 millimoles) of monoallylamine, 0.53 g (5.4 millimoles) of diallylamine 0.63 g (4.6 millimoles) of triallylamine. The conversion based on allyl alcohol was 21.5% and the selectivity was 96.8%.

Aufarbeitung

  1. additionwere added
  2. customwas carried out at 110° C.

Quellen und Nachweise

ORD-Eintrag
ord-692e55a0d76041d3a7e1aa34e763b27d
Quelldatensatz
uspto-grants-1990_07
Patentnummer
US04942261

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