CAS 5911-08-0 (Chloromethyl)cyclopropane (HCID 80013)

Names & identifiers

Preferred name: (Chloromethyl)cyclopropane
IUPAC: chloromethylcyclopropane
English name: Cylopropylmethyl chloride
Molecular formula: C4H7Cl
Molecular weight: 90.55

Names & synonyms

(Chloromethyl)cyclopropane5911-08-0Cyclopropane, (chloromethyl)-chloromethyl-cyclopropaneJ7OKQCC0KWEINECS 227-632-1Cyclopropyl methyl chlorideDTXSID40207854CYCLOPROPYLCARBINYL CHLORIDERefChem:406007DTXCID90130345227-632-1

Show more names

CPMClTEDI-003Cylopropylmethyl chlDesidustat Impurity 67cylopropylMethyl lorideCyclopropylmethychlorideCylopropylmethylchloride

chloromethylcyclopropaneCylopropylmethyl chlorideCyclopropylmethyl chloride(Chloromethyl)cyclopropane (Technical Grade)MFCD00001307chloromethyl cyclopropanechloromethylcyclo-propane(chloromethyl) cyclopropane

Database identifiers

CAS: 5911-08-0
PubChem CID: 80013
DTXSID: DTXSID40207854
UNII: J7OKQCC0KW
EC Number: 227-632-1
Nikkaji: J225I

Properties

Computed structural properties

XLogP: 1.6
Topological polar surface area: 0 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 0
Rotatable bonds: 1
Heavy atoms: 5
Formal charge: 0
Complexity: 30.6

Experimental & physicochemical properties

SpringerMaterials PropertiesSchoenflies notation

Physicochemical properties

Melting point: -91 °C · -91°C
Boiling point: 87 · 87-89 °C(lit.)
Density: 0.98 g/mL · 0.98 g/mL at 25 °C(lit.)
refractive index: 20 · n20/D 1.435(lit.)
Flash point: 29 °F · 29 °F
storage temp.: 2 · Inert atmosphere,2-8°C
solubility: soluble in Chloroform, Methanol
form: clear liquid
color: Colorless to Almost colorless
Water Solubility: Not miscible in water.
BRN: 635697 · 635697
InChI: InChI=1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2
InChIKey: ZVTQWXCKQTUVPY-UHFFFAOYSA-N
SMILES: C1(CCl)CC1
CAS DataBase Reference: 5911 · 5911-08-0(CAS DataBase Reference)
FDA UNII: 7 OKQCC0KW · J7OKQCC0KW
NIST Chemistry Reference: (Chloromethyl)cyclopropane(5911-08-0)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS07
Signal word: Danger
Hazard statements: 225 · H225-H315-H319-H335
Precautionary statements: 210 · P210-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: F,Xi
Risk Statements: 11 · 11-36/37/38
Safety Statements: 16 · 16-26-36/37/39
RIDADR: 1993 · UN 1993 3/PG 2
WGK Germany: 3 · 3
HazardClass: 3 · 3
PackingGroup: II
HS Code: 29035990 · 29035990
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 2 Flam · Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
REACH Registrations: Active
Limited Quantities: 1 L · 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Chemical: Cyclopropane, (chloromethyl)-

Status: Active Update: 29-03-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/23460

Cyclopropyl methyl chloride: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Safety data

PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 3
ridadr: UN 1993 3/PG 2
hs_code: 29035990
risk_code: 11-36/37/38
Signal word: Danger
Symbol(GHS): GHS02,GHS07
hazard_code: F,Xi
safety_code: 16-26-36/37/39
hazard_class: 3
Storage Class: 3 - Flammable liquids
packing_group: II
target organs: Respiratory system
Hazard statements: H225-H315-H319-H335
Limited Quantities: 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
REACH Registrations: Active
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P210-P302+P352-P305+P351+P338

Chemistry & industry

Applications

Uses(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.

General Description(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.