Carbon Monoxide → Methyl 3-oxocyclopent-1-enecarboxylate

HRID 2001578

Reaction equation

HRID 2001578 reaction equation
[C-:1]#[O+:2].[CH3:3][OH:4].Cc1ccc(S(O[C:5]([CH2:10][CH2:9][C:7]2=[O:8])=[CH:6]2)(=O)=O)cc1>>[CH3:3][O:4][C:1]([C:5]([CH2:10][CH2:9][C:7]1=[O:8])=[CH:6]1)=[O:2]

Participants

9

Reactant 3

HCID 281Carbon MonoxideHCID 887MethanolHCID 86196686(3-Oxocyclopenten-1-yl) 4-methylbenzenesulfonate

Product 1

HCID 11029917Methyl 3-oxocyclopent-1-enecarboxylate

Reagents, catalysts & solvents 5

HCID 11430Potassium CarbonateReagentHCID 167845palladium(II) acetateCatalystHCID 634876Binap, (A+-)-CatalystHCID 887MethanolSolventHCID 117669-PhenylanthraceneInternal standard

Conditions

Temperature
110 °C

Sources & evidence

ORD record
ord-9a2cc50574e14a67ae19149263cd8309
Source dataset
39k HTE dataset from Pfizer
Original link
View source

Linked notes

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