Ammonium → 4-Bromo-1-fluoronaphthalene-2-carbaldehyde

HRID 308417

Reaction equation

HRID 308417 reaction equation
[Br:16][c:17]1[cH:18][cH:19][c:20]([F:27])[c:21]2[cH:22][cH:23][cH:24][cH:25][c:26]12.[CH2:11]([Li:12])[CH2:13][CH2:14][CH3:15].[CH3:1][C:2]1([CH3:3])[CH2:4][CH2:5][CH2:6][C:7]([CH3:8])([CH3:9])[NH:10]1.[CH3:35][N:36]([CH3:37])[CH:38]=[O:39].[Cl-:28].[NH4+:29].[O:30]1[CH2:31][CH2:34][CH2:33][CH2:32]1>>[Br:16][c:17]1[cH:18][c:19]([CH:31]=[O:30])[c:20]([F:27])[c:21]2[cH:22][cH:23][cH:24][cH:25][c:26]12

Participants

8

Reactant 7

HCID 223AmmoniumHCID 312ChlorideHCID 6228DimethylformamideHCID 8028TetrahydrofuranHCID 130352,2,6,6-TetramethylpiperidineHCID 676471-Bromo 4-fluoronaphthaleneHCID 178418339Butyllithium

Product 1

HCID 534400924-Bromo-1-fluoronaphthalene-2-carbaldehyde

Sources & evidence

ORD record
ord-cbf87ce4f22c4122a991e0bf95067c7d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Linked notes

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