Diethyl Ether → (5-Methyl-2-thienylethynyl)trimethylsilane

HRID 694634

Reaction equation

HRID 694634 reaction equation
[CH3:14][CH2:15][N:16]([CH2:17][CH3:18])[CH2:19][CH3:20].[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[CH:6].[CH3:21][CH2:22][O:23][CH2:24][CH3:25].[Cu:67][I:68].[I:7][c:8]1[s:9][c:10]([CH3:13])[cH:11][cH:12]1.[Pd:26]([Cl:27])[Cl:28].[c:29]1([P:30]([c:31]2[cH:32][cH:33][cH:34][cH:35][cH:36]2)[c:37]2[cH:38][cH:39][cH:40][cH:41][cH:42]2)[cH:43][cH:44][cH:45][cH:46][cH:47]1.[c:48]1([P:49]([c:50]2[cH:51][cH:52][cH:53][cH:54][cH:55]2)[c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)[cH:62][cH:63][cH:64][cH:65][cH:66]1>>[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[C:6][c:8]1[s:9][c:10]([CH3:13])[cH:11][cH:12]1

Participants

8

Reactant 7

HCID 3283Diethyl EtherHCID 8471TriethylamineHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 1400962-Iodo-5-methylthiophene

Product 1

HCID 14643579(5-Methyl-2-thienylethynyl)trimethylsilane

Sources & evidence

ORD record
ord-4b622744e63747e29a939087f9d40bf2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Linked notes

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