1-(2-Methoxyphenyl)isoquinoline → 1-[2-Methoxy-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]isoquinoline
反応式
COc1ccccc1-c1nccc2ccccc12>C(=NN(Cc1ccccc1)Cc1ccccc1)c1ccccn1.C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>COc1cccc(B2OC(C)(C)C(C)(C)O2)c1-c1nccc2ccccc12参加物
7
反応物 1
生成物 1
試薬・触媒・溶媒 5
反応条件
- 温度
- 50 °C
実験手順
Following the general procedure, precipitation from the reaction crude with hexane and trituration afforded 9i (159 mg, 88 %) as a pale solid.
出典と根拠
- ORDレコード
- ord-2dd73b1c305947e1a593c90545f7d2d2
- 出典データセット
- Borylation dataset from Roche
反応ノート
読み込み中…