Methacrylic Acid → Hexadecyl methacrylate

HRID 1923414

反応式

HRID 1923414 の反応式
CN(C(F)(O)C(F)(F)F)S([C:6](F)(F)[C:7](F)(F)[C:8](F)(F)[C:9](F)(F)F)(=O)=O.C1C2NC3C(=CC=CC=3)SC=2C=CC=1.COC1C=C(O)C=CC=1O.C(O)(=O)C(C)=C.C(O)(=O)C=C.CS(O)(=O)=O.OS(C(F)(F)F)(=O)=O.[C:74]([O:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:86][CH2:87][CH2:88][CH2:89][CH2:90][CH2:91]CCCCCCCCCC)(=[O:78])[C:75]([CH3:77])=[CH2:76]>O.CCCCCCC>[C:74]([O:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:9][CH2:8][CH2:7][CH3:6])(=[O:78])[C:75]([CH3:77])=[CH2:76].[C:74]([O:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:86][CH2:87][CH2:88][CH2:89][CH2:90][CH2:91][CH2:9][CH2:8][CH2:7][CH3:6])(=[O:78])[C:75]([CH3:77])=[CH2:76]

参加物

12

反応物 8

HCID 4093Methacrylic AcidHCID 6395Methanesulfonic AcidHCID 6581Acrylic AcidHCID 7108PhenothiazineHCID 62406Trifluoromethanesulfonic acidHCID 699882-Methoxybenzene-1,4-diolHCID 30342582-Propenoic acid, 2-methyl-, docosyl esterHCID 86761564N-methylperfluorobutanesulfonamidoethanol

生成物 2

HCID 17235Hexadecyl methacrylateHCID 18510Decyl methacrylate

試薬・触媒・溶媒 2

HCID 962Water溶媒HCID 8900Heptane溶媒

実験手順

MeFBSEMA was made according to the method of U.S. Pat. No. 6,664,354 (Savu), Example 2, Parts A and B, incorporated herein by reference, except using 3420 kg of N-methylperfluorobutanesulfonamidoethanol, 1.6 kg of phenothiazine, 2.7 kg of methoxyhydroquinone, 1400 kg of heptane, 980 kg of methacrylic acid (instead of acrylic acid), 63 kg of methanesulfonic acid (instead of triflic acid), and 7590 kg of water in Part B. Behenyl Methacrylate was obtained from Ciba Specialty Chemicals, Basel, Switzerland, under the trade designation “CIBA AGEFLEX FM22”. Decyl methacrylate and hexadecyl methacrylate were obtained from Monomer-Polymer & Dajac Labs, Feasterville, Pa. Dodecyl methacrylate was obtained from Avocado Organics, Ward Hill, Mass. 2,2,3,3,4,4,4-Heptafluorobutyl 2-methylacrylate (FBMA) was prepared as described in paragraph 47 of EP1311637 (Savu et al.), published Apr. 5, 2006. 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl 2-methylacrylate (FOMA) was obtained from 3M Company, St. Paul, Minn., under the designation “L-9179”. N-Ethylperfluorooctanesulfonamidoethyl acrylate (EtFOSEA) was obtained from 3M Company under the trade designation “FX-13”.

出典と根拠

ORDレコード
ord-f306b42f6dc3432f925183e847557d9f
出典データセット
uspto-grants-2012_05
特許番号
US08176981B2

関連ノート

読み込み中…