Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-

HRID 22093

反応式

HRID 22093 の反応式
O[C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[Na].N#N.C1OC1CO.Cl>CS(C)=O.OCC(CO)O>[C:8]([OH:10])(=[O:9])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][CH:2]=[CH:12][CH:11]=1

参加物

8

反応物 5

HCID 313Hydrochloric AcidHCID 3224-Coumaric acidHCID 947NitrogenHCID 11164GlycidolHCID 5360545Sodium

生成物 1

HCID 87842-Propenoic acid, 3-phenyl-

試薬・触媒・溶媒 2

HCID 679Dimethyl Sulfoxide溶媒HCID 753Glycerol溶媒

実験手順

2.8 g of p-hydroxy cinnamic acid was dissolved in 3 ml of DMSO, and 10 mg of sodium was added. The mixture was stirred and heated to 90° C. under a flow of N2 gas. 5.0 g of glycidol was added gradually, the heating and agitation was carried out for 1 hours, neutralized by adding hydrochloric acid and then the adduct of cinnamic acid and glycerin was obtained.

出典と根拠

ORDレコード
ord-6b9e768bb16f4b5ebfd44303c1c7b17e
出典データセット
uspto-grants-1995_06
特許番号
US05426210

関連ノート

読み込み中…