Azobisisobutyronitrile → Methacrylic Acid

HRID 346293

反応式

HRID 346293 の反応式
[C:1](OF)(=[O:4])[CH:2]=C.[C:7]([O-:12])(=[O:11])[C:8]([CH3:10])=[CH2:9].CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[C:7]([OH:12])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:7]([O:12][CH2:2][CH2:1][OH:4])(=[O:11])[C:8]([CH3:10])=[CH2:9]

参加物

6

反応物 3

HCID 6547AzobisisobutyronitrileHCID 87595MethacrylateHCID 21909953Fluoro acrylate

生成物 2

HCID 4093Methacrylic AcidHCID 133602-Hydroxyethyl Methacrylate

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

This example illustrates conjoint use of the fluoro acrylate and methacrylate. 75.81 g (40.8 wt. %) of the perfluoroalkyl methacrylate (DuPont's Zonyl-TM), 72.3 g (38.9 wt. %) of the perfluoroalkyl acrylate (Hoechst-Celanese NUVA HF), 17.61 g (9.5 wt. %) of methacrylic acid, and 19.98 g (10.8 wt. %) of 2-hydroxyethyl methacrylate were polymerized in 300 ml THF, using 0.55 g AIBN as initiator, employing above-described procedure. Yield: 79.1%.

出典と根拠

ORDレコード
ord-cd1e6f295915444e88010f80a06c0170
出典データセット
uspto-grants-1991_10
特許番号
US05061769

関連ノート

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