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Phthalic Anhydride → Maleic Anhydride

HRID 441503
ノート
印刷プレビュー

反応式

HRID 441503 の反応式
[C:1]1(=[O:7])[O:6][C:4](=[O:5])[CH:3]=[CH:2]1.[C:8]1(=O)OC(=O)CC1.C1(=O)OC(=O)C=C1C.C1(=O)OC(=O)CC1=C.ClC1C(OC(=O)C=1)=O.CC1CC(=O)OC1=O.C(C1CC(=O)OC1=O)CC.C(C1CC(=O)OC1=O)CCCCC.C1(C2C(OC(=O)C=2)=O)C=CC=CC=1.CC1(C)C(CC2C=CC=CC=2)C(=O)OC1=O.C1(=O)OC(=O)C2=CC=CC=C12.C1(=O)OC(=O)C2CCC=CC12.C1(=O)OC(=O)C2CCCCC12>>[C:4]1(=[O:5])[O:6][C:1](=[O:7])[CH:2]=[CH:3]1.[CH:1]1[CH2:8][CH2:4][CH2:3][CH:2]=1.[O:6]1[CH:1]=[CH:2][CH:3]=[CH:4]1
参加物実験手順出典と根拠反応ノート

参加物

16

反応物 13

HCID 6811Phthalic AnhydrideHCID 7922Succinic anhydrideHCID 7923Maleic Anhydride2 回HCID 12012Citraconic AnhydridesHCID 20051Methylsuccinic anhydrideHCID 66772Chloromaleic anhydrideHCID 75110Itaconic Anhydride
HCID 85689
Hexahydrophthalic anhydride
HCID 99174Phenylmaleic anhydride
HCID 5127355Propylsuccinic anhydride
HCID 126561692,5-Furandione, 3-hexyldihydro-
HCID 127266013a,4,5,7a-Tetrahydro-2-benzofuran-1,3-dione
HCID 86734988alpha,alpha-Dimethylbenzylsuccinic anhydride

生成物 3

HCID 7923Maleic AnhydrideHCID 8029FuranHCID 8882Cyclopentene

実験手順

Desirable nonplasticizing monoanhydrides include maleic anhydride; succinic anhydride; and the one to six carbon alkyl, the chloro, the phenyl, the benzyl and the mono and dimethylbenzyl derivatives of maleic anhydride such as citraconic anhydride; itaconic anhydride; chloromaleic anhydride; methyl succinic anhydride; propylsuccinic anhydride, hexylsuccinic anhydride; phenylmaleic anhydride; α,α-dimethylbenzylsuccinic anhydride; and the like. Also desirable monoanhydrides include phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, and their chloro, methyl and cyano derivatives, and the like, such as methyltrihydrophthalic anhydride; 1,2-dicarboxylic- 4-chlorocyclohexane anhydride; 1,2-dicarboxylic-4-cyanocyclohexane anhydride; and the like. Further desirable monoanhydrides include 1,2-dicarboxylic-cyclopentane; 1,2-dicarboxyliccycloheptane; and the three-ringed anhydrides formed by the Diels-Alder condensation of maleic anhydride with cyclopentene, furan, or their methyl derivatives, such as bicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride (Nadic anhydride); a mixture of methylbicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride isomers (Nadic methyl anhydride); 7-oxabicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride; and the like.

出典と根拠

ORDレコード
ord-cde1ca1f3b224c48a26c86540227f85c
出典データセット
uspto-grants-1977_08
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04041004

反応ノート

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