N,N-Dimethylaniline → HCID 178507928、化合物

反応式

CN1CC[O:5][CH2:4][CH2:3]1.C[N:9]([CH3:16])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.C([N:21](CCCC)CCCC)CCC.C(N(C)C)CCCCCCCCC.C(N(C)C)CCCCC.[NH2-].[Na+].C1(C([Na])(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[H-].[Na+].[O-]CC.[K+].[Na].[OH-].[K+]>>[NH2:21][C:16]1[CH:3]=[C:4]([OH:5])[C:11]2[C:10](=[CH:15][CH:14]=[CH:13][CH:12]=2)[N:9]=1

参加物

反応物 11

HCID 949N,N-Dimethylaniline

HCID 7622Tributylamine

HCID 79724-Methylmorpholine

HCID 14797Potassium Hydroxide

HCID 24533Sodium amide

HCID 24758Sodium hydride

HCID 70711N,N-Dimethyl-N-decylamine

HCID 78090N,N-Dimethylhexylamine

実験手順

Repetition of this reaction but replacing triethylamine with N-methylmorpholine, N,N-dimethylaniline, tri-n-butylamine, N-decyl dimethylamine, N-hexyl dimethylamine, sodamide, triphenylmethyl sodium, sodium hydride, potassium ethoxide, metallic sodium, or potassium hydroxide, affords the same product.