Acetophenone → Acetaldehyde

HRID 614705

反応式

HRID 614705 の反応式
[C:1]1(=[O:7])CCCC[CH2:2]1.[C:8]1(=[O:13])C[CH2:11][CH2:10][CH2:9]1.C(C(CC(C)C)=O)C(C)C.CC1(C)CC(C)CC(=O)C1.C[C:35]([C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1)=[O:36]>CC(CC(C)C)=O.C(C(CC)=O)C.CC(CC)=O.CC(C)=O>[CH:1](=[O:7])[CH3:2].[CH:8](=[O:13])[CH2:9][CH2:10][CH3:11].[CH:35](=[O:36])[CH:37]([CH3:42])[CH3:38].[CH:35](=[O:36])[C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1

参加物

13

反応物 5

HCID 7410AcetophenoneHCID 7958Isobutyl ketoneHCID 7967CyclohexanoneHCID 8452CyclopentanoneHCID 133983,3,5-Trimethylcyclohexanone

生成物 4

HCID 177AcetaldehydeHCID 240BenzaldehydeHCID 261ButanalHCID 6561Isobutyraldehyde

試薬・触媒・溶媒 4

HCID 180Acetone溶媒HCID 6569Methyl Ethyl Ketone溶媒HCID 7288Ethyl ketone溶媒HCID 7909Methyl Isobutyl Ketone溶媒

実験手順

Optionally, the polyaminoamide-polyaminoimidazoline mixtures described above, which are to be used according to the present invention, can be reacted with common ketones such as acetone, methyl-ethyl ketone, di-ethyl ketone, methyl-isobutyl ketone, cyclohexanone, cyclopentanone, di-isobutyl ketone, 3,3,5-trimethyl cyclohexanone, or methyl-phenyl ketone, or with aldehydes such as acetaldehyde, butyraldehyde, isobutyraldehyde, or benzaldehyde to form the corresponding Schiff bases or enamines.

出典と根拠

ORDレコード
ord-d86be34e8b3e4a9587888377e234ae88
出典データセット
uspto-grants-1979_03
特許番号
US04146520

関連ノート

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