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Hydrogen Bromide → Silver bromide

HRID 616806
ノート
印刷プレビュー

反応式

HRID 616806 の反応式
[OH-].[Na+].[C:3]([OH:16])(=[O:15])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[BrH:17].[N+]([O-])([O-])=O.[Ag+:22]>C1(C)C=CC=CC=1>[C:3]([O-:16])(=[O:15])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[Ag+:22].[Ag:22][Br:17]
参加物実験手順後処理出典と根拠反応ノート

参加物

7

反応物 4

HCID 260Hydrogen BromideHCID 3893Lauric AcidHCID 14798Sodium HydroxideHCID 24470Silver Nitrate

生成物 2

HCID 66199Silver bromideHCID 9904644Silver laurate

試薬・触媒・溶媒 1

HCID 1140Toluene
溶媒

実験手順

One liter of an aqueous solution of 20 g of sodium hydroxide was mixed with 2 liters of toluene having dissolved therein 120 g of lauric acid, and the mixture was emulsified using a high speed rotary stirrer. To the emulsion, 500 ml of a 0.4% by weight aqueous solution of hydrobromic acid was added, and the mixture was again emulsified. To the resulting emulsion, 500 ml. of an aqueous solution of 85 g of silver nitrate was added to form silver laurate and silver bromide simultaneously. The toluene phase containing the silver nitrate and the silver bromide was separated from the aqueous phase, and dispersed in 2.4 Kg of a 15% by weight isopropanol solution of polyvinyl butyral using a high speed rotary stirrer. The resulting dispersion will be referred to hereinafter as a silver salt polymer dispersion.

後処理

  1. dissolutiondissolved

出典と根拠

ORDレコード
ord-601173edfb844c25b00d3916c94a49a5
出典データセット
uspto-grants-1978_02
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04076534

反応ノート

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