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Azobisisobutyronitrile → Diethyl carbonate ethylene carbonate

HRID 2059533
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HRID 2059533 반응식
C(OC)(=O)C(C)=C.C(OCC1CCC2OC2C1)(=O)C=C.[C:21]1(=[O:26])[O:25][CH2:24][CH2:23][O:22]1.N(C(C)(C)C#N)=NC(C)(C)C#N.[C:39](=[O:46])([O:43][CH2:44][CH3:45])[O:40][CH2:41][CH3:42]>>[C:21]1(=[O:26])[O:25][CH2:24][CH2:23][O:22]1.[C:39](=[O:46])([O:43][CH2:44][CH3:45])[O:40][CH2:41][CH3:42]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 5

HCID 6547Azobisisobutyronitrile2회HCID 6658Methyl MethacrylateHCID 7303Ethylene carbonateHCID 7766Diethyl CarbonateHCID 12860205(3,4-Epoxycyclohexyl)methyl Acrylate (stabilized with HQ)

생성물 1

HCID 66954576Diethyl carbonate ethylene carbonate

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온도
70 °C

실험 절차

60.0 g of methyl methacrylate, 20.0 g of 3,4-epoxycyclohexylmethyl acrylate, 226.6 g of ethylene carbonate and 0.24 g of 2,2′-azobis(isobutyronitrile) were placed in a 500 mL capacity three-necked flask equipped with a refluxing condenser and stirred and mixed for 30 minutes while nitrogen gas was introduced into the flask. The mixture was heated to 70° C. and radical polymerization was carried out at the temperature over 8 hours. The resulting reaction mixture was cooled to 40° C. 226.6 g of diethyl carbonate and 0.24 g of 2,2′-azobis(isobutyronitrile) were added to the reaction mixture and the resulting mixture was again heated to 70° C. for carrying out radical polymerization at the temperature for another 8 hours. The resulting reaction mixture was cooled to 40° C. thereby to obtain a solution of a polymer in a concentration of 15% by weight in a solvent of ethylene carbonate/diethyl carbonate mixture.

후처리

  1. customequipped with a refluxing condenser
  2. additionmixed for 30 minutes while nitrogen gas
  3. additionwas introduced into the flask
  4. customradical polymerization
  5. customThe resulting reaction mixture
  6. temperaturewas cooled to 40° C
  7. temperaturethe resulting mixture was again heated to 70° C.
  8. custompolymerization at the temperature for another 8 hours
  9. customThe resulting reaction mixture
  10. temperaturewas cooled to 40° C.

출처 및 근거

ORD 기록
ord-0764a475bbd14958a0dfcc290f1a43c0
출처 데이터셋
uspto-grants-2012_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08277897B2

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