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Azobisisobutyronitrile → Diethyl carbonate ethylene carbonate

HRID 2059535
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HRID 2059535 반응식
C(OC)(=O)C(C)=C.C(OCC1(CC)COC1)(=O)C(C)=C.C(OCC1CCC2OC2C1)(=O)C=C.[C:34]1(=[O:39])[O:38][CH2:37][CH2:36][O:35]1.[C:40](=[O:47])([O:44][CH2:45][CH3:46])[O:41][CH2:42][CH3:43].N(C(C)(C)C#N)=NC(C)(C)C#N>>[C:34]1(=[O:39])[O:38][CH2:37][CH2:36][O:35]1.[C:40](=[O:47])([O:44][CH2:45][CH3:46])[O:41][CH2:42][CH3:43]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

7

반응물 6

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 7303Ethylene carbonateHCID 7766Diethyl CarbonateHCID 11159706(3-Ethyloxetan-3-yl)methyl 2-methylprop-2-enoateHCID 12860205(3,4-Epoxycyclohexyl)methyl Acrylate (stabilized with HQ)

생성물 1

HCID 66954576
Diethyl carbonate ethylene carbonate

반응 조건

온도
70 °C

실험 절차

60.0 g of methyl methacrylate, 16.0 g of 3-ethyl-3-oxetanylmethyl methacrylate, 4.0 g of 3,4-epoxycyclohexylmethyl acrylate, 226.6 g of ethylene carbonate and 0.15 g N,N′-azobis(isobutyronitrile) were placed in a 500 Ml Capacity three-necked flask equipped with a refluxing condenser, and stirred and mixed for 30 minutes while nitrogen gas was introduced into the flask. Then the resulting mixture was heated to 70° C. and radical polymerization was carried out over 8 hours at the temperature. The resulting reaction mixture was cooled to 40° C. 226.6 g of diethyl carbonate and 0.15 g of 2,2′-azobis(isobutyronitrile) were added to the reaction mixture and the resulting mixture was again heated to 70° C. to carry out radical polymerization at the temperature for another 8 hours. Then the resulting reaction mixture was cooled to 40° C. to obtain a solution of a polymer in a concentration of 15% by weight in a solvent of ethylene carbonate/diethyl carbonate mixture.

후처리

  1. customequipped with a refluxing condenser
  2. additionmixed for 30 minutes while nitrogen gas
  3. additionwas introduced into the flask
  4. customradical polymerization
  5. customThe resulting reaction mixture
  6. temperaturewas cooled to 40° C
  7. temperaturethe resulting mixture was again heated to 70° C.
  8. custompolymerization at the temperature for another 8 hours
  9. customThen the resulting reaction mixture
  10. temperaturewas cooled to 40° C.

출처 및 근거

ORD 기록
ord-55a59668d8d44351aca57b22bf4a9d6f
출처 데이터셋
uspto-grants-2012_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08277968B2

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