Acetic Anhydride → Citronellyl Acetate

HRID 2164189

반응식

HRID 2164189 반응식
[CH3:1][CH:2]([CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10])[CH2:3][CH2:4][OH:5].[C:12](OC(=O)C)(=[O:14])[CH3:13]>N1C=CC=CC=1>[C:12]([O:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][CH2:7][CH:8]=[C:9]([CH3:10])[CH3:11])(=[O:14])[CH3:13]

참가 물질

4

반응물 2

HCID 7918Acetic AnhydrideHCID 8842Citronellol

생성물 1

HCID 9017Citronellyl Acetate

시약·촉매·용매 1

HCID 1049Pyridine용매

실험 절차

100 Grams of 3,7-dimethyloct-6-en-1-ol is dissolved in 150 ml. of pyridine and 100 ml. of acetic anhydride and left at room temperature for about 48 hours. Then the mixture is extracted with ether and the ethereal extracts washed with water, 10% aqueous HCl and brine to yield 1-acetoxy-3,7-dimethyloct-6-ene which is purified by distillation.

후처리

  1. extractionThen the mixture is extracted with ether
  2. washthe ethereal extracts washed with water, 10% aqueous HCl and brine

출처 및 근거

ORD 기록
ord-bd39ca3e5fdc410baafd6f53f8e929f7
출처 데이터셋
uspto-grants-1979_01
특허 번호
US04137273

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