O-Cresol → 2,6-Dimethylphenol

HRID 435218

반응식

HRID 435218 반응식
[C:1]1([CH3:8])[C:6]([OH:7])=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:9]1(O)C=CC=CC=1.COC.[Si]=O.[O-2].[Ba+2]>[O-2].[Fe+2].[O-2].[V+5].[O-2].[O-2].[O-2].[O-2].[V+5].O>[C:6]1([OH:7])[C:5]([CH3:9])=[CH:4][CH:3]=[CH:2][C:1]=1[CH3:8]

참가 물질

9

반응물 5

HCID 335O-CresolHCID 996PhenolHCID 8254Dimethyl EtherHCID 66241Silicon oxide (SiO)HCID 9855530Barium Oxide Nanoparticle Dispersion

생성물 1

HCID 113352,6-Dimethylphenol

시약·촉매·용매 3

HCID 449809Ferrous oxide촉매HCID 178419084HCID 178419084, 화합물촉매HCID 962Water용매

실험 절차

A mixture of o-cresol and phenol, dimethyl ether and water in a molar ratio of 1:2:2.6 were reacted as described in Example 1. The catalyst contained iron oxide, vanadium oxide, silicon oxide and barium oxide in a molar ratio of 100:2:10:0.1. After working up, 2.6-xylenol was obtained with a selectivity of 99%.

후처리

  1. customwere reacted

출처 및 근거

ORD 기록
ord-0e577805cbc34edb9d3509a4195c1f30
출처 데이터셋
uspto-grants-1983_08
특허 번호
US04400557

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